By Andrei V. Kiselev, Yakov I. Yashin (auth.)
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Additional resources for Gas-Adsorption Chromatography
20 150· C \ v •. :I ~ Ri t"rl () f) ~ rJ) 9 8 7 10 n I I ,. 0''-'' 134 134 t-Butylbenzene ... · .... s -Butylbenzene . .... 120 120 120 128 158 144 · .... Isopropylbenzene Propylbenzene. . . . Mesitylene ......... n-Nonane . . . . . , .... n-Nonanoic acid · .... 5 . 106 Ethylbenzene ........ 106 m-Xylene . . . . . n-Caprylic acid. . . . 2 130 n-Capryl alcohol . . . 120 Dimethylaniline . . . . 120 Acetophenone . . . . 114 n-Octane . . . . . 1 175 202 M Benzoic acid.
These equations describe closely the nonspecific adsorption of hydrocarbons by zeolites, and also the. specific adsorption of CO 2, zeolites having inhomogeneous surfaces in relation to this [145-147] (in this case, the heat of adsorption decreases as () increases). o ....... 0--- a. mmole/g Fig. 28. Adsorption isotherms for Xe for a) LiX and b) Nax zeolites at various temperatures, and relation of Qa for Xe to uptake a for c) LiX and d) Nax. Curves arecalculated from Eq. (II, 1). Point symbols are experimental data.
The order of release of these six-membered compounds is due mainly to differences in spatial strueture. There is only nonspecific intel'action with the adsorbent, whieh is almost independent of the dipole or quadrupole moment and of the local charge distribution in the bonds or links. This is clear from Table 2 [3, 4, 32}, which gives the number of carbon atoms n, the moleeular weight M, the boiling point T, the dipole moment Jl, total polarizability a, Vs for graphitized carbon black (proportional to the absolute values of the Henry constants) at several temperatures, and Qo (initial differential heat of adsorption).
Gas-Adsorption Chromatography by Andrei V. Kiselev, Yakov I. Yashin (auth.)