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Cyanogen can be obtained by the solution of potassium ferrocyanide. 1 * 8 electrolysis of a 3 Comp. , 82, 1360. Lieb. , 113, 135. See potassium ferrocyanide. p. 45. OF ALIPHATIC COMPOUNDS. Acid. Hydrocyanic Electrosynthesis obtained hydrocyanic reaction is, Berthelot : by passing the acid spark through a mixture of acetylene The 45 however, reversible. l electric and nitrogen. On allowing the electric spark to act on hydrocyanic-acid gas it was decomposed into acetylene and nitrogen. Hydro- also obtained electric cyanic acid is by passing the spark through mixtures of ethylene or aniline vapor with nitrogen, acetylene with nitric oxide (Huntington a ), nitrogen with benzol (Perkin Electrolysis: In cyanic acid breaks sulphuric-acid up 3 ), etc.

5. n-Dodecane-dicarboxylic acid potassium 6. the ethyl- salt of suberic acid. n-Deca-hexane-dicarboxylic acid from the ethyl- potassium If from salt of sebacic acid. the ethyl-potassium salts of substituted acids are taken as a starting-point it is possible to obtain disubstituted acids according to the above reaction. 1. Ethyl-potassium methyl-malonate gave the two symmetrical dimethyl-succinic acids, having the melting-points 193 2. and 121. Ethyl-pctassium ethyl-malonate gave the corre- OF ALIPHATIC COMPOUNDS.

69, 279. Grundriss d. Elektrochemie, 1895, The formation p. 292. 1 6 ELECTROLYSIS AND ELECTROSYNTHESIS be explained by assuming either the of ethane can direct oxidation of the acetic acid, or the decomposition of the anion, CH COO\ _ c H 4- 2 CO U CH COO/- ^""t 3 '' 8 Kkule advanced a theory based on the phenom- l ena of decomposition, and from this deduced certain formulae which make i* possible to predict the nature products resulting from the electrolysis of monobasic and dibasic acids of the fatty acid series.

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Electrolysis and electrosynthesis of organic compounds by Walther Lob

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