New PDF release: Advanced Gas Sensing: The Electroadsorptive Effect and

By Martin Bögner, Theodor Doll (auth.), Theodor Doll (eds.)

ISBN-10: 144198612X

ISBN-13: 9781441986122

ISBN-10: 1461346479

ISBN-13: 9781461346470

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Additional resources for Advanced Gas Sensing: The Electroadsorptive Effect and Related Techniques

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The bond between the COlatl. 07 eV. CO desorption was observed during TDS investigations on polycrystalline Ga203 after exposure to C~ [9]. 52 Chapter 2 Cads + Olall. 07 eV The calculated bond energy of CO is consistent with the observed desorption maximum in the TDS spectra (Fig. 4). CO2 and H20 have been observed in desorption. The desorption energies have been evaluated during the MBRS investigations. Cads + 20la1t. 0 eV The MBRS results are confirmed by the posItIOn of the desorption maximums of the TDS spectra using the following relation [10]: EalRTmax = In(faT maxl~ -3,64) The desorption energy Ea and the frequency factor fa are results of the MBRS measurements.

These parameters are determined by an optimisation process using empirical data. The parametrisation as it is implemented in MOPAC93 [4] is used for the calculations. The way the parameters are optimised is described for 0 and H [5] and for gallium [6]. Gallium oxide exhibits a C2Im symmetry [7] with two different sites of gallium atoms. One is centred in the middle of a tetrahedron, the others are centred in the middle of an octahedron. We simulated the (100) plane of GaZ03' This plane is one of the surfaces produced by cleavage of GaZ03 and is the growth axis of single crystals [8].

Kowalkowski, Conductance, work funktion and catalytic activity of Sn02-based gas sensors, Sens. Act. B, 3, 205-214, 1991 [6] [7] [8] [9] [10] [II] [12] [13] P. Bergveld, Development of an ion-sensitive solid state device for neurophysio-I ogical measurements, IEEE Trans. Biomed. , 17,70-71,1970 T. Doll, I. Eisele, Gas Detection with Work Function Sensors, in Chemical Microsensors and Applications, Stephanus Buttgenbach, Editor, Proceedings of SPIE Yol. 3539, 96-106,1998 Th. Wolkenstein, The Electron Theory of Catalysis on Semiconductors, McMillan, .

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Advanced Gas Sensing: The Electroadsorptive Effect and Related Techniques by Martin Bögner, Theodor Doll (auth.), Theodor Doll (eds.)


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